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31.
Moe MK Huber S Svenson J Hagenaars A Pabon M Trümper M Berger U Knapen D Herzke D 《Chemosphere》2012,89(7):869-875
For several decades, perfluorooctane sulfonate (PFOS) has widely been used as a fluorinated surfactant in aqueous film forming foams used as hydrocarbon fuel fire extinguishers. Due to concerns regarding its environmental persistence and toxicological effects, PFOS has recently been replaced by novel fluorinated surfactants such as Forafac®1157, developed by the DuPont company. The major component of Forafac®1157 is a 6:2 fluorotelomer sulfonamide alkylbetaine (6:2 FTAB), and a link between the trade name and the exact chemical structure is presented here to the scientific community for the first time. In the present work, the structure of the 6:2 FTAB was elucidated by 1H, 13C and 19F nuclear magnetic resonance spectroscopy and high-resolution mass spectrometry. Moreover, its major metabolites from blue mussel (Mytilus edulis) and turbot (Scophthalmus maximus) and its photolytic transformation products were identified. Contrary to what has earlier been observed for PFOS, the 6:2 FTAB was extensively metabolized by blue mussel and turbot exposed to Forafac®1157. The major metabolite was a deacetylated betaine species, from which mono- and di-demethylated metabolites also were formed. Another abundant metabolite was the 6:2 fluorotelomer sulfonamide. In another experiment, Forafac®1157 was subjected to UV-light induced photolysis. The experimental conditions aimed to simulate Arctic conditions and the deacetylated species was again the primary transformation product of 6:2 FTAB. A 6:2 fluorotelomer sulfonamide was also formed along with a non-identified transformation product. The environmental presence of most of the metabolites and transformation products was qualitatively demonstrated by analysis of soil samples taken in close proximity to an airport fire training facility. 相似文献
32.
低碳消费偏好与低碳产品需求分析 总被引:5,自引:0,他引:5
低碳消费方式是低碳经济的重要环节,本文对低碳消费偏好和低碳产品需求及其影响因素作了理论分析和实证研究.首先对低碳产品的消费偏好进行了分析,低碳产品消费偏好的两个最重要特征是二元价值结构的产品和超越基本价值的消费偏好,在此基础上构建了低碳产品效用函数.然后根据低碳产品效用函数给出了低碳产品的一般需求模式,结合低碳产品置信度变量的引进,构建了一个具体的低碳产品需求函数,并对低碳产品需求函数进行分析,揭示了低碳产品需求的一些基本性质.为了验证低碳消费理论分析的结论,做了低碳产品消费的问卷调查.对问卷调查进行统计分析,结果表明:收入越高,对低碳产品支付的价格就越高;低碳产品的环境价值置信度越高,意愿支付价格就越商;低碳产品碳排放量降低越多,低碳产品需求价格就越高.最后,结合以上分析,从低碳宣传和公益广告、设立低碳产品标准、鼓励低碳产品技术研发角度提出了促进低碳消费发展的政策建议. 相似文献
33.
MASAMI FUKUSHIMA KENJI TATSUMI 《Journal of environmental science and health. Part. B》2013,48(4):357-367
The coupling products (CPs), which were formed via the peroxosulfate catalyzed oxidation of pentachlorophenol (PCP) with iron(III)-tetrakis(sulfonatophenyl)porphyrin (Fe(III)-TPPS) in the presence of hydroxypropyl-β -cyclodextrin (HP-β -CD) or HP-γ -CD, were separated by ultrafiltration from the reaction mixture. When the percentages of chlorine species in the reaction mixture were calculated from the concentrations of organic chlorine in the reaction mixture and CPs, 10–25% of chlorine species in the reaction mixture was organic chlorine that was incorporated into CDs. Analyses of the CPs by pyrolysis-GC/MS (Py-GC/MS) and 13C NMR showed that the PCP-derived products were covalently incorporated into the CDs. To evaluate the acute toxicity of the CPs, a Microtox® test was examined. Toxicities of the CPs were reduced slightly, compared to the controls (PCP alone and PCP + reaction blanks). In the reaction blanks, mesaconic acid (MA) moieties were detected as a result of the oxidation of CDs in the absence of PCP. Thus, factors in the toxicities, detected in the CPs, can be attributed to the oxidation products derived from CDs, such as MA, as well as the PCP-derived products incorporated into the CDs. 相似文献
34.
A review of recent literature in the fields of operations, supply chain, and management indicates there is on-going interest in improving new product development (NPD) performance. Three-dimensional concurrent engineering (3DCE), the simultaneous design of product, process and supply chain have been proposed as a way to improve traditional NPD outcomes, such as reduced time to market, lower costs, and improved customer acceptance. There appears to be a lesser concern associated with the environmental impacts of new products. Environmentally responsible manufacturing (ERM) on new product development focuses on reduced emissions, hazardous materials elimination, and lower product weight without sacrificing functionality. This paper explores the following issue: will employing 3DCE to integrate NPD and ERM yield better benefits than the separate and uncoordinated application of environmental goals and NPD initiatives? 相似文献
35.
无排泥运行MBR处理不同浓度氨氮废水及其生物特性 总被引:1,自引:1,他引:0
考察了水力停留时间(HRT)为10 h时无排泥运行下膜-生物反应器(MBR)处理不同浓度氨氮无机废水的运行性能及微生物特性.结果表明,在处理NH4+-N≤500 mg/L的废水时,氨氮转化率可达99%且反应器内微生物增长缓慢,比硝化速率从0.2kg/(kg·d)升至0.52 kg/(kg·d);当NH4+-N≥700 mg/L时,出水亚硝酸氮和氨氮相继出现明显累积,比硝化速率随之下降至0.4kg/(kg·d)以下,反应器内生物量从3 200 mg/L上升至6 700 mg/L.反应器中的氨氧化菌维持在107CFU/mL,亚硝酸盐氧化菌从106CFU/mL下降至103CFU/mL.系统内的溶解性微生物产物(以TOC表示)升至65 mg/L后保持稳定,出水TOC一直维持在3~4mg/L;细胞外分泌物(EPS)在膜的截流作用下随运行时间的延长积累至600 mg/L. 相似文献
36.
37.
污水污泥裂解目标产物及残焦促进植物生长的研究 总被引:1,自引:1,他引:0
研究了污水污泥的低温裂解特性,考察了裂解终温和干燥到一定程度后污泥含水率对裂解产物分布及产物性质的影响,并分析了裂解产物中最合适的目标产物形式.经过分析比较,最终确定以污泥裂解残焦为目标产物并通过与普通土壤混拌进行了栽种大蒜和测试大蒜重金属浓度水平的实验,并考察残焦中重金属向植物迁移的情况.结果表明,干燥到一定程度的污水污泥在550℃下裂解时残焦的产率在40%以上,其中灰分含量在60%~65%之间,富含氮、 磷、 钾.该残焦中重金属含量符合有关土地使用规定,能明显促进大蒜植株的生长,实验组平均株高比普通组高出3~4 cm;但是快速生长的大蒜植株中重金属浓度略有增加.研究表明残焦是合适的污水污泥裂解目标产物,具有土地使用的前景,能够用于促进非食用目的的植物的生长. 相似文献
38.
嗜热厌氧乙醇菌在纤维素酒精生产中的作用 总被引:2,自引:1,他引:1
以热纤维梭菌 (Clostridium thermocellum LQRI)和嗜热厌氧乙醇菌(Thermoanaerobacter ethanolicus X514和Thermoanaerobacter pseudoethanolicus 39E)为对象,以不同浓度纤维素Avicel为底物,研究嗜热厌氧乙醇菌加入LQR... 相似文献
39.
Kathryn H. WinnebeckAuthor Vitae 《Journal of Cleaner Production》2011,19(5):464-476
Alternatives assessment is becoming increasingly popular to evaluate the potential environmental and human health hazards of materials. A three step process was used to identify and evaluate alternative products for a children's furniture manufacturer. An alternatives assessment framework was developed to analyze alternative mattresses. The framework specifically addresses those environmental and safety attributes applicable to the product and the product components in accordance with the product’s intended use. The result of the assessment allowed the manufacturer to select the most environmentally friendly alternative and eliminate polyvinyl chloride from their product. 相似文献
40.